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Changes of crystallinity and spherulite morphology in isotactic polypropylene after rolling and heat Changes of crystallinity and spherulite morphology in isotactic polypropylene after rolling and heat

Changes of crystallinity and spherulite morphology in isotactic polypropylene after rolling and heat

  • 期刊名字:北京科技大學學報(英文版)
  • 文件大?。?/li>
  • 論文作者:Juan Jia,Weimin Mao,Dierk Raab
  • 作者單位:School of Materials Science and Engineering,Max-Planck-Institut für Eisenforschung
  • 更新時間:2023-02-07
  • 下載次數(shù):
論文簡介

The spherulite morphology of the rolled and subsequent heat-treated isotaetic polypropylene (iPP) was observed by polarized microscopy, and the crystallinity evolution of materials was also measured by the wide angle X-ray scattering (WAXS). Rolling led to the oblate spherulites in the deformed iPP samples. The sheared crystalline lamellae broke apart into sets of crystalline blocks during rolling. As a result, the crystallinity of the iPP samples was greatly reduced during deformation, which induced the unclear spherulites and spherulite boundaries. Subsequent heat treatment resulted in the strong recrystallization of the rolled iPP samples. But the recrystallization in this work only meant the rearrangement of the macromolecule along the unbroken crystalline lamellae and the existing small crystalline blocks in the deformed spherulites. Heat treatment did not change the shape of the spherulites formed during deformation. The recrystallization also resulted in very clear spherulites and spherulite boundaries.

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