Preparation and property of a novel soluble electron transport POSS-based hybrid material

期刊名字：中國化學(xué)快報（英文版）
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論文作者：Xin Wang，Juan Shen，Jin Cui Wu，
作者單位：School of Chemistry and Chemical Engineering,College of Material Science and Engineering & State Key Laboratory of Chemi
更新時間：2023-02-12
下載次數(shù)：次

論文簡介

A novel POSS-based organic/inorganic hybrid covalently attached at molecular level, 2-(4-(allyloxy)phenyl)-5-(4-(octyloxy)phenyl)-1,3,4-oxadiazole-POSS (6) (abbreviated as oxadiazole-POSS) was synthesized by Pt (dcp) catalyst. The hybrid was soluble in common organic solvents such as CHCl3, toluene, C2H4Cl2, and THF. Its structures and properties were characterized and evaluated with FTIR, 1H NMR, 13C NMR, 29Si NMR, EA, TGA, DSC, GPC, and CV, respectively. The results show that the novel hybrid possesses high thermal stability and good electron injection ability.

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