Oxidation of Hecogenin and Diosgenin Derivatives with Dimethyldioxirane

期刊名字：中國(guó)化學(xué)快報(bào)（英文版）
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論文作者：Bao Kun ZHU，Hong Bin ZHANG，Yu
作者單位：The School of Pharmacy,The School of Chemistry
更新時(shí)間：2023-02-14
下載次數(shù)：次

論文簡(jiǎn)介

Diacetyl derivative of hecogenin 1 was oxidized to unsaturated ketone 5 via allylic alcohol 3 when it reacted with dimethyldioxirane (DMDO). The structure of 3 was confimed by X-ray crystal analysis and the highly regioselectivity of DMDO to different olefin bonds was also observed when diosgenin derivative 6 was treated with DMDO.

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