Mechanism and prediction of failure of diamond films deposited on various substrates by HFCVD
- 期刊名字:中國(guó)有色金屬學(xué)會(huì)會(huì)刊(英文版)
- 文件大?。?/li>
- 論文作者:ZHOU Ling-ping,SUN Xin-yuan,LI
- 作者單位:College of Material Science and Engineering
- 更新時(shí)間:2023-02-27
- 下載次數(shù):次
Diamond films were deposited on the WC-Co cemented carbide and Si3N4 ceramic cutting tool substrates by hot-filament-assisted chemical vapour deposition. The adherence property of diamond films was estimated using the critical load (Pcr) in the indentation test. The adhesive strength of diamond films is related to the intermediate layer between the film and the substrate. Poor adhesion of diamond films to polished cemented carbide substrate is owing to the formation of graphite phase in the interface. The adhesion of diamond films deposited on acid etched cemented carbide substrate is improved, and the peeling-off of the films often happens in the loosen layer of WC particles where the cobalt element is nearly removed. The diamond films' adhesion to cemented carbide substrate whose surface layer is decarbonizated is strengthened dramatically because WC phase forms by reaction between the deposited carbon and tungsten in the surface layer of substrates during the deposition of diamond, which results in chemical combination in the film-substrate interface. The adhesion of diamond films to silicon nitride substrate is the firmest due to the formation of chemical combination of the SiC intermediate layer in the interfaces. In the piston-turning application, the diamond-coated Si3N4 ceramic and the cemented carbide cutting tools usually fail in the form of collapsing of edge and cracking or flaking respectively. They have no built-up edge(BUE) as long as coating is intact.As it wears through, BUE develops and the cutting force on it increases 1 - 3 times than that prior to failure. This can predict the failure of diamond-coated cutting tools.
-
C4烯烴制丙烯催化劑 2023-02-27
-
煤基聚乙醇酸技術(shù)進(jìn)展 2023-02-27
-
生物質(zhì)能的應(yīng)用工程 2023-02-27
-
我國(guó)甲醇工業(yè)現(xiàn)狀 2023-02-27
-
石油化工設(shè)備腐蝕與防護(hù)參考書十本免費(fèi)下載,絕版珍藏 2023-02-27
-
四噴嘴水煤漿氣化爐工業(yè)應(yīng)用情況簡(jiǎn)介 2023-02-27
-
Lurgi和ICI低壓甲醇合成工藝比較 2023-02-27
-
甲醇制芳烴研究進(jìn)展 2023-02-27
-
精甲醇及MTO級(jí)甲醇精餾工藝技術(shù)進(jìn)展 2023-02-27
