Material effect of inner-detectors on the performances of the BESⅢ Electromagnetic Calorimeter (EMC)is investigated.The BESⅢ Time-Of-Flight counters(TOF)have been utilized to improve the energy resolution and detection efficiency for photons after a careful energy calibration.A matching algorithm between TOF and EMC energy deposits is developed,and the effects of beam-related background are discussed.The energy resolution is improved and the photon detection efficiency can be increased by the combined measurement of EMC and TOF detectors.