Oxidation of propane over substituted Keggin phosphomolybdate salts

期刊名字：天然氣化學(xué)（英文版）
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論文作者：T. Mazari，C. Roch. Marchal，S.
作者單位：Laboratoire de Chimie du Gaz Naturel,ILV-UMR 8180 CNRS-Université de Versailles-St Quentin-en-Yvelines
更新時間：2023-02-15
下載次數(shù)：次

論文簡介

Ammonium salts,(NH_4)_6HPMo_(11) MO_(40) (M=Ni,Co,Fe),have been investigated for the oxidation of propane,with molecular oxygen,at temperature ranging between 380 ℃ and 420 ℃ after in-situ pre-treatment performed at two heating rate of 5 or 9 ℃/min. They were characterized by BET method,XRD,~(31)p NMR,UV-Vis and IR techniques. The catalysts were found active in the propane oxidation and selective to propene or acrolein,in particular for samples pre-treated with the heating rate of 9 ℃/min.

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