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Synthesis Gas Production from Natural Gas on Supported Pt Catalysts Synthesis Gas Production from Natural Gas on Supported Pt Catalysts

Synthesis Gas Production from Natural Gas on Supported Pt Catalysts

  • 期刊名字:天然氣化學(xué)(英文版)
  • 文件大?。?/li>
  • 論文作者:Mariana M. V. M. Souza
  • 作者單位:NUCAT/PEQ/COPPE,Escola de Química
  • 更新時間:2022-09-22
  • 下載次數(shù):
論文簡介

Auto-thermal reforming of methane, combining partial oxidation and reforming of methane with CO2 or steam, was carried out with Pt/Al2O3, Pt/ZrO2 and Pt/CeO2 catalysts, in a temperature range of 300-900 ℃. The auto-thermal reforming occurs in two simultaneous stages, namely, total combustion of methane and reforming of the unconverted methane with steam and CO2, with the O2 conversion of 100% starting from 450 ℃. For combination with CO2 reforming, the Pt/CeO2 catalyst showed the lowest initial activity at 800 ℃, and the highest stability over 40 h on-stream. This catalyst also presented the best performance for the reaction with steam at 800 ℃. The higher resistance to coke formation of the catalyst supported on ceria is due to the metal-support interactions and the higher mobility of oxygen in the oxide lattice.

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