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Oxidation behavior of Ni(Co)CrAlYHf(Si) coatings on DS superalloy at 1 150 ℃ Oxidation behavior of Ni(Co)CrAlYHf(Si) coatings on DS superalloy at 1 150 ℃

Oxidation behavior of Ni(Co)CrAlYHf(Si) coatings on DS superalloy at 1 150 ℃

  • 期刊名字:中國(guó)有色金屬學(xué)會(huì)會(huì)刊(英文版)
  • 文件大小:
  • 論文作者:HUANG Zhao-hui,TAN Yong-ning,Z
  • 作者單位:National Defence Key Laboratory for Advanced High Temperature Structural Materials
  • 更新時(shí)間:2023-02-15
  • 下載次數(shù):
論文簡(jiǎn)介

Two Ni(Co)CrAlY coatings were deposited by EB-PVD method on a DS superalloy of Ni-Al-Cr-Co-W-Mo-Ta-Hf system. SEM, XEDS and XRD were used to study the oxidation behavior of the coatings. The two coatings show a good protection for the DS superalloy. The results of the isothermal oxidation test at 1 150 ℃ for 100 h show that the oxidation tendency obeys the parabolic law, and the oxidation rate constant Kp of the coated specimens decreases to about 1/3 of that for the bare superalloy. After oxidation, a continuous alumina-based scale is formed at the surfaces of the coated samples. Y2O3, NiO and SiO2 are also detectable in the oxide scale. A large number of Al in the coating is consumed due to high-temperature diffusion and oxidation reactions, and the NiAl phases in the coating are almost completely transformed to Ni3Al phases. For the Hf-bearing coating, some HfO2 particles exist at the interface between the coating and the substrate. Although internal oxidation occurs, the coating still shows a good adhesion with the superalloy substrate even after oxidation for 100 h. For the bare DS superalloy, after 100 h oxidation at 1 150 ℃, only discontinuous alumina-based oxide particles exist on the surface. Oxide spallation occurs for the bare alloy.

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